X-ray crystal structures of discrete and polymeric chiral silver complexes of monoterpenoid alkenes

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X-Ray Crystal Structures of Discrete and Polymeric Chiral Silver Complexes of Monoterpenoid Alkenes

X-Ray crystal structures are reported for five silver(I) complexes of four monoterpenoid alkenes. Discrete mononuclear complexes of the chiral alkenes (1S)-(-)-α-pinene and (1S)(-)-β-pinene with silver perchlorate and silver hexafluorophosphate are described. The achiral diene γ-terpinene forms a discrete mononuclear adduct with silver hexafluorophosphate and a two-dimensional polymeric network...

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x-ray, crystal structure and solution phase studies of a polymeric srii compound

in the crystal structure of the title polymeric compound, [c42h38n6o33sr5.2(h2o)]n, five independent metal atoms (sr1-sr5) have different coordination environments. the sr1 and sr5 atoms are nine coordinated and feature distorted tricapped trigonal-prismatic and capped square-antiprismatic geometries, respectively. the rest srii atoms have eight coordination numbers. these units are connected v...

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ژورنال

عنوان ژورنال: Journal of Organometallic Chemistry

سال: 2006

ISSN: 0022-328X

DOI: 10.1016/j.jorganchem.2005.11.046